Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

Fateme Banishoeib; A. Henckens; S. Fourier; G. Vanhooyland; M. Breselge; Jean V. Manca; T. J. Cleij; L. Lutsen; D. Vanderzande; Le Huong Nguyen; Helmut Neugebauer; Niyazi Serdar Sariciftci

doi:10.1016/j.tsf.2007.08.001

Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

Fateme Banishoeib, A. Henckens, S. Fourier, G. Vanhooyland, M. Breselge, Jean V. Manca, T. J. Cleij, L. Lutsen, D. Vanderzande^*, Le Huong Nguyen, Helmut Neugebauer, Niyazi Serdar Sariciftci

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

58 Citations (Web of Science)

Abstract

Poly-(2,5-thienylene vinylene) (ptv) derivatives have been synthesised via the “dithiocarbamate precursor route” in good yield and satisfactory molecular weight. Structural characterisations of the conjugated ptv polymers reveal an optical band gap around 1.8 ev. Organic field effect transistors and organic based photovoltaic devices were made with the plain ptv, via a precursor approach. More specifically, solar cells were produced using a blend of the precursor ptv polymer and pcbm (1-(3-methoxycarbonyl) propyl-1-phenyl [6,6] c61) at various ratios, converted in situ in thin film. A promising power efficiency of 0.76% was achieved.

Original language	English
Pages (from-to)	3978-3988
Journal	Thin Solid Films
Volume	516
Issue number	12
DOIs	https://doi.org/10.1016/j.tsf.2007.08.001
Publication status	Published - 30 Apr 2008
Externally published	Yes

Keywords

low band gap
conjugated polymer
precursor polymer
poly-(2,5-Thienylene Vinylene)

Access to Document

10.1016/j.tsf.2007.08.001

Cite this

Banishoeib, F., Henckens, A., Fourier, S., Vanhooyland, G., Breselge, M., Manca, J. V., Cleij, T. J., Lutsen, L., Vanderzande, D., Nguyen, L. H., Neugebauer, H., & Sariciftci, N. S. (2008). Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics. Thin Solid Films, 516(12), 3978-3988. https://doi.org/10.1016/j.tsf.2007.08.001

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abstract = "Poly-(2,5-thienylene vinylene) (ptv) derivatives have been synthesised via the “dithiocarbamate precursor route” in good yield and satisfactory molecular weight. Structural characterisations of the conjugated ptv polymers reveal an optical band gap around 1.8 ev. Organic field effect transistors and organic based photovoltaic devices were made with the plain ptv, via a precursor approach. More specifically, solar cells were produced using a blend of the precursor ptv polymer and pcbm (1-(3-methoxycarbonyl) propyl-1-phenyl [6,6] c61) at various ratios, converted in situ in thin film. A promising power efficiency of 0.76% was achieved.",

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T1 - Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

AU - Banishoeib, Fateme

AU - Henckens, A.

AU - Fourier, S.

AU - Vanhooyland, G.

AU - Breselge, M.

AU - Manca, Jean V.

AU - Cleij, T. J.

AU - Lutsen, L.

AU - Vanderzande, D.

AU - Nguyen, Le Huong

AU - Neugebauer, Helmut

AU - Sariciftci, Niyazi Serdar

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AB - Poly-(2,5-thienylene vinylene) (ptv) derivatives have been synthesised via the “dithiocarbamate precursor route” in good yield and satisfactory molecular weight. Structural characterisations of the conjugated ptv polymers reveal an optical band gap around 1.8 ev. Organic field effect transistors and organic based photovoltaic devices were made with the plain ptv, via a precursor approach. More specifically, solar cells were produced using a blend of the precursor ptv polymer and pcbm (1-(3-methoxycarbonyl) propyl-1-phenyl [6,6] c61) at various ratios, converted in situ in thin film. A promising power efficiency of 0.76% was achieved.

KW - low band gap

KW - conjugated polymer

KW - precursor polymer

KW - poly-(2,5-Thienylene Vinylene)

U2 - 10.1016/j.tsf.2007.08.001

DO - 10.1016/j.tsf.2007.08.001

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SN - 0040-6090

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