Some Irregularities in the Evaluation of Surface Parameters of Solid Materials by Inverse Gas Chromatography

The London dispersive component of the surface energy of solid particles, their specific interactions, and Lewis acid-base parameters were usually calculated by using the inverse gas chromatography technique at infinite dilution. Serious irregularities were committed by some authors when using the Schultz method or Dorris-Gray relation. We proved that these methods cannot be used because they did not consider the important role of the temperature on variations in the surface area of solvents. We corrected in this paper some recent results by using new relations of the surface area of organic probes depending on the temperature and by using different molecular models using different geometries and mathematical calculations. The application of our new thermal model gave more precise results of the dispersive energy and Lewis's acid-base constants of solid particles. The new thermal model was applied to several solid surfaces such as Ni-MOF-74, MgO, ZnO, TiO , and Zn(OH) . The obtained results showed a stronger Lewis basicity of MgO solid substrate and higher Lewis acidity of the Ni-MOF-74 surface.