@article{4c49e462d9e94c0cad17adf542ca5528,
title = "Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diols via pressure hydrogenation of potentially biobased platform molecules using Kn{\"o}lker-type catalysts",
abstract = "The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Knolker-type iron catalyst. The catalyst exhibits a high selectivity for ketone reduction, and does not induce dehydration. Moreover, by using different substituents of the ligand, the cis-trans ratio of the products can be affected substantially. A decent compatibility of this catalytic system with various structurally related substrates is demonstrated.",
keywords = "IRON CATALYST, CONFORMATIONAL-ANALYSIS, COMPLEXES SYNTHESIS, BIOMASS, REDUCTION, TRANSFORMATION, CONVERSION, EFFICIENT, MECHANISM, KETONES",
author = "{van Slagmaat}, {Christian A. M. R.} and Teresa Faber and Chou, {Khi Chhay} and Freire, {Alfonso J. Schwalb} and Darya Hadavi and Peiliang Han and Quaedflieg, {Peter J. L. M.} and Verzijl, {Gerard K. M.} and Alsters, {Paul L.} and {De Wildeman}, {Stefaan M. A.}",
note = "Funding Information: This work was performed within the framework of the public-private knowledge institute of Chemelot InSciTe and is funded by contributions from the European Regional Development Fund (ERDF) within the framework of OP-Zuid and with contributions from the Dutch provinces of Noord-Brabant and Limburg and the Dutch Ministry of Economy. We gratefully acknowledge these agencies for their financial support. We also would like to thank Prof. Maarten Honing for offering his mass spectrometry equipment for our use. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = aug,
day = "7",
doi = "10.1039/d1dt01252e",
language = "English",
volume = "50",
pages = "10102--10112",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "29",
}