@article{f97e0690616546acb4f3610a09b141fd,
title = "Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium- and Terbium-[1]Ruthenocenophane Complexes",
abstract = "We report the first f-block-ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal-prismatic geometry stabilizes the magnetic ground state in the case of Dy3+ and results in a larger barrier to magnetization reversal (U), a decrease in U is observed for the case of Tb3+.",
keywords = "f-block chemistry, inorganic, magnetization dynamics, organometallic, single-molecule magnet, SINGLE-MOLECULE MAGNET, CRYSTAL, BIS(PHTHALOCYANINATO)TERBIUM, CONTRACTION, RELAXATION, ANISOTROPY, RADII",
author = "Risica, {Gabrielle M.} and Veaceslav Vieru and Wilkins, {Branford O.} and Latendresse, {Trevor P.} and Reibenspies, {Joseph H.} and Bhuvanesh, {Nattamai S.} and Wylie, {Gregory P.} and Chibotaru, {Liviu F.} and Michael Nippe",
note = "Funding Information: M.N. is grateful for support of this project by the National Science Foundation (CHE‐1753014) and general financial support through The Welch Foundation (A‐1880). V.V. acknowledges the postdoctoral fellowship of Fonds Wetenschappelijk Onderzoek Vlaanderen (FWO, Flemish Science Foundation). Funding Information: M.N. is grateful for support of this project by the National Science Foundation (CHE-1753014) and general financial support through The Welch Foundation (A-1880). V.V. acknowledges the postdoctoral fellowship of Fonds Wetenschappelijk Onderzoek Vlaanderen (FWO, Flemish Science Foundation). Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2020",
month = aug,
day = "3",
doi = "10.1002/anie.202003759",
language = "English",
volume = "59",
pages = "13335--13340",
journal = "Angewandte Chemie-International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "32",
}