Efficient Functionalization of Additives at Supramolecular Material Surfaces

Olga J. G. M. Goor; Henk M. Keizer; Anne L. Bruinen; Moniek G. J. Schmitz; Ron M. Versteegen; Henk M. Janssen; Ron M. A. Heeren; Patricia Y. W. Dankers

doi:10.1002/adma.201604652

Efficient Functionalization of Additives at Supramolecular Material Surfaces

Olga J. G. M. Goor, Henk M. Keizer, Anne L. Bruinen, Moniek G. J. Schmitz, Ron M. Versteegen, Henk M. Janssen, Ron M. A. Heeren, Patricia Y. W. Dankers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

66 Downloads (Pure)

Abstract

Selective surface modification reactions can be performed on additives that are supramolecularly incorporated into supramolecular materials. Hereby, processing of the material, that regularly requires harsh processing conditions (i.e., the use of organic solvents and/or high temperatures), and functionalization can be decoupled. Moreover, high-resolution depth profiling by time-of-flight (ToF) secondary-ion mass spectrometry clearly shows distinct differences in surface and bulk material composition.

Original language	English
Article number	1604652
Number of pages	8
Journal	Advanced Materials
Volume	29
Issue number	5
DOIs	https://doi.org/10.1002/adma.201604652
Publication status	Published - 2 Feb 2017

Keywords

DIELS-ALDER
THERMOPLASTIC ELASTOMERS
DEGRADABLE POLYMERS
CLICK REACTIONS
NANOFIBERS
LIGATION
POLYMERIZATION
CYCLOADDITIONS
DIENOPHILES
FABRICATION

Access to Document

10.1002/adma.201604652

Full TextFinal published version, 3.11 MBLicence: Taverne

Cite this

@article{237a95b8e7314de790d0d7a276a49832,

title = "Efficient Functionalization of Additives at Supramolecular Material Surfaces",

abstract = "Selective surface modification reactions can be performed on additives that are supramolecularly incorporated into supramolecular materials. Hereby, processing of the material, that regularly requires harsh processing conditions (i.e., the use of organic solvents and/or high temperatures), and functionalization can be decoupled. Moreover, high-resolution depth profiling by time-of-flight (ToF) secondary-ion mass spectrometry clearly shows distinct differences in surface and bulk material composition.",

keywords = "DIELS-ALDER, THERMOPLASTIC ELASTOMERS, DEGRADABLE POLYMERS, CLICK REACTIONS, NANOFIBERS, LIGATION, POLYMERIZATION, CYCLOADDITIONS, DIENOPHILES, FABRICATION",

author = "Goor, {Olga J. G. M.} and Keizer, {Henk M.} and Bruinen, {Anne L.} and Schmitz, {Moniek G. J.} and Versteegen, {Ron M.} and Janssen, {Henk M.} and Heeren, {Ron M. A.} and Dankers, {Patricia Y. W.}",

year = "2017",

month = feb,

day = "2",

doi = "10.1002/adma.201604652",

language = "English",

volume = "29",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

number = "5",

}

TY - JOUR

T1 - Efficient Functionalization of Additives at Supramolecular Material Surfaces

AU - Goor, Olga J. G. M.

AU - Keizer, Henk M.

AU - Bruinen, Anne L.

AU - Schmitz, Moniek G. J.

AU - Versteegen, Ron M.

AU - Janssen, Henk M.

AU - Heeren, Ron M. A.

AU - Dankers, Patricia Y. W.

PY - 2017/2/2

Y1 - 2017/2/2

N2 - Selective surface modification reactions can be performed on additives that are supramolecularly incorporated into supramolecular materials. Hereby, processing of the material, that regularly requires harsh processing conditions (i.e., the use of organic solvents and/or high temperatures), and functionalization can be decoupled. Moreover, high-resolution depth profiling by time-of-flight (ToF) secondary-ion mass spectrometry clearly shows distinct differences in surface and bulk material composition.

AB - Selective surface modification reactions can be performed on additives that are supramolecularly incorporated into supramolecular materials. Hereby, processing of the material, that regularly requires harsh processing conditions (i.e., the use of organic solvents and/or high temperatures), and functionalization can be decoupled. Moreover, high-resolution depth profiling by time-of-flight (ToF) secondary-ion mass spectrometry clearly shows distinct differences in surface and bulk material composition.

KW - DIELS-ALDER

KW - THERMOPLASTIC ELASTOMERS

KW - DEGRADABLE POLYMERS

KW - CLICK REACTIONS

KW - NANOFIBERS

KW - LIGATION

KW - POLYMERIZATION

KW - CYCLOADDITIONS

KW - DIENOPHILES

KW - FABRICATION

U2 - 10.1002/adma.201604652

DO - 10.1002/adma.201604652

M3 - Article

SN - 0935-9648

VL - 29

JO - Advanced Materials

JF - Advanced Materials

IS - 5

M1 - 1604652

ER -