Synthesis of mono- and bi-layer zeolite films on alumina substrates

Ali Said; Habiba Nouali; Lionel Limousy; Patrick Dutournie; Ludovic Josien; Joumana Toufaily; Tayssir Hamieh; T. Jean Daou

doi:10.1016/j.crci.2015.09.018

Synthesis of mono- and bi-layer zeolite films on alumina substrates

Ali Said
, Habiba Nouali
, Lionel Limousy
, Patrick Dutournie
, Ludovic Josien
, Joumana Toufaily
, Tayssir Hamieh
, T. Jean Daou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Bilayer zeolite films ZSM-5/ZSM-5, ZSM-5/EMC-1 and NaY/ZSM-5 were synthesized on α-alumina plates. The bottom ZSM-5 or faujasite Y (NaY) zeolite layers were obtained by direct hydrothermal synthesis or by using a seeding step followed by a secondary growth method, respectively, while the secondary growth method was used for the synthesis of all the top zeolite layers. A complete characterization of the obtained materials is proposed using various techniques, such as X-ray diffraction, scanning electron microscopy, X-ray fluorescence and nitrogen sorption measurements. Continuous and highly crystallized bi-layer zeolite films with thicknesses around 11-18 μm were obtained.

Original language	English
Pages (from-to)	486-495
Number of pages	10
Journal	Comptes Rendus Chimie
Volume	19
Issue number	4
DOIs	https://doi.org/10.1016/j.crci.2015.09.018
Publication status	Published - Apr 2016
Externally published	Yes

Keywords

Zeolite
MR
FAU
Zeolite film
Bi-layered film
Crystallisation
Secondary growth method
MFI FILMS
MOLECULAR DECONTAMINATION
ENERGETIC PERFORMANCES
CERAMIC SUPPORTS
DIRECTING AGENTS
MEMBRANES
COATINGS
BEA
CRYSTALLIZATION
SILICALITE-1

Access to Document

10.1016/j.crci.2015.09.018Licence: CC BY-NC-ND

Cite this

@article{0fe387b73ce8412bacc7cc4a79caf31c,

title = "Synthesis of mono- and bi-layer zeolite films on alumina substrates",

abstract = "Bilayer zeolite films ZSM-5/ZSM-5, ZSM-5/EMC-1 and NaY/ZSM-5 were synthesized on α-alumina plates. The bottom ZSM-5 or faujasite Y (NaY) zeolite layers were obtained by direct hydrothermal synthesis or by using a seeding step followed by a secondary growth method, respectively, while the secondary growth method was used for the synthesis of all the top zeolite layers. A complete characterization of the obtained materials is proposed using various techniques, such as X-ray diffraction, scanning electron microscopy, X-ray fluorescence and nitrogen sorption measurements. Continuous and highly crystallized bi-layer zeolite films with thicknesses around 11-18 μm were obtained.",

keywords = "Zeolite, MR, FAU, Zeolite film, Bi-layered film, Crystallisation, Secondary growth method, MFI FILMS, MOLECULAR DECONTAMINATION, ENERGETIC PERFORMANCES, CERAMIC SUPPORTS, DIRECTING AGENTS, MEMBRANES, COATINGS, BEA, CRYSTALLIZATION, SILICALITE-1",

author = "Ali Said and Habiba Nouali and Lionel Limousy and Patrick Dutournie and Ludovic Josien and Joumana Toufaily and Tayssir Hamieh and Daou, \{T. Jean\}",

year = "2016",

month = apr,

doi = "10.1016/j.crci.2015.09.018",

language = "English",

volume = "19",

pages = "486--495",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Academie des sciences",

number = "4",

}

TY - JOUR

T1 - Synthesis of mono- and bi-layer zeolite films on alumina substrates

AU - Said, Ali

AU - Nouali, Habiba

AU - Limousy, Lionel

AU - Dutournie, Patrick

AU - Josien, Ludovic

AU - Toufaily, Joumana

AU - Hamieh, Tayssir

AU - Daou, T. Jean

PY - 2016/4

Y1 - 2016/4

N2 - Bilayer zeolite films ZSM-5/ZSM-5, ZSM-5/EMC-1 and NaY/ZSM-5 were synthesized on α-alumina plates. The bottom ZSM-5 or faujasite Y (NaY) zeolite layers were obtained by direct hydrothermal synthesis or by using a seeding step followed by a secondary growth method, respectively, while the secondary growth method was used for the synthesis of all the top zeolite layers. A complete characterization of the obtained materials is proposed using various techniques, such as X-ray diffraction, scanning electron microscopy, X-ray fluorescence and nitrogen sorption measurements. Continuous and highly crystallized bi-layer zeolite films with thicknesses around 11-18 μm were obtained.

AB - Bilayer zeolite films ZSM-5/ZSM-5, ZSM-5/EMC-1 and NaY/ZSM-5 were synthesized on α-alumina plates. The bottom ZSM-5 or faujasite Y (NaY) zeolite layers were obtained by direct hydrothermal synthesis or by using a seeding step followed by a secondary growth method, respectively, while the secondary growth method was used for the synthesis of all the top zeolite layers. A complete characterization of the obtained materials is proposed using various techniques, such as X-ray diffraction, scanning electron microscopy, X-ray fluorescence and nitrogen sorption measurements. Continuous and highly crystallized bi-layer zeolite films with thicknesses around 11-18 μm were obtained.

KW - Zeolite

KW - MR

KW - FAU

KW - Zeolite film

KW - Bi-layered film

KW - Crystallisation

KW - Secondary growth method

KW - MFI FILMS

KW - MOLECULAR DECONTAMINATION

KW - ENERGETIC PERFORMANCES

KW - CERAMIC SUPPORTS

KW - DIRECTING AGENTS

KW - MEMBRANES

KW - COATINGS

KW - BEA

KW - CRYSTALLIZATION

KW - SILICALITE-1

U2 - 10.1016/j.crci.2015.09.018

DO - 10.1016/j.crci.2015.09.018

M3 - Article

SN - 1631-0748

VL - 19

SP - 486

EP - 495

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

IS - 4

ER -

Synthesis of mono- and bi-layer zeolite films on alumina substrates

Abstract

Keywords

Access to Document

Fingerprint

Cite this