Etude des propriétés acido-basiques et énergie interfaciale des oxydes et hydroxydes métalliques

T. Hamieh

doi:10.1016/S1251-8069(97)81154-2

Etude des propriétés acido-basiques et énergie interfaciale des oxydes et hydroxydes métalliques

T. Hamieh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Inverse gas chromatography (IGC) at infinite dilution was used to determine the dispersive component γSD of the surface energy of some metallic oxides and hydroxides. The zero charge point (ZCP) of these solids was determined by potentiometric measurements, whereas their isoelectric point (IEP) was calculated by the zeta potential technique in aqueous medium. This study allowed us to determine the acid-base properties (in terms of the Brönstedt acid-base concept) of the solids. The interfacial energy of the oxides and hydroxides was obtained from the results of Söhnel. The new linear relationships found between the γSD of solids and their ZCP (or their IEP, or pH of their aqueous suspension) allowed us to obtain the polar component of the surface energy as a function of the ZCP or IEP of these solids.

Original language	English
Pages (from-to)	353-362
Number of pages	10
Journal	Comptes Rendus de l'Académie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy
Volume	325
Issue number	6
DOIs	https://doi.org/10.1016/S1251-8069(97)81154-2
Publication status	Published - 1 Sept 1997
Externally published	Yes

Keywords

inverse gas chromatography
surface energy
zero charge point

Access to Document

10.1016/S1251-8069(97)81154-2

http://adsabs.harvard.edu/abs/1997CRASB.325..353H

Cite this

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title = "Etude des propri{\'e}t{\'e}s acido-basiques et {\'e}nergie interfaciale des oxydes et hydroxydes m{\'e}talliques",

abstract = "Inverse gas chromatography (IGC) at infinite dilution was used to determine the dispersive component γSD of the surface energy of some metallic oxides and hydroxides. The zero charge point (ZCP) of these solids was determined by potentiometric measurements, whereas their isoelectric point (IEP) was calculated by the zeta potential technique in aqueous medium. This study allowed us to determine the acid-base properties (in terms of the Br{\"o}nstedt acid-base concept) of the solids. The interfacial energy of the oxides and hydroxides was obtained from the results of S{\"o}hnel. The new linear relationships found between the γSD of solids and their ZCP (or their IEP, or pH of their aqueous suspension) allowed us to obtain the polar component of the surface energy as a function of the ZCP or IEP of these solids.",

keywords = "inverse gas chromatography, surface energy, zero charge point",

author = "T. Hamieh",

year = "1997",

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doi = "10.1016/S1251-8069(97)81154-2",

language = "English",

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pages = "353--362",

journal = "Comptes Rendus de l'Acad{\'e}mie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy",

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TY - JOUR

T1 - Etude des propriétés acido-basiques et énergie interfaciale des oxydes et hydroxydes métalliques

AU - Hamieh, T.

PY - 1997/9/1

Y1 - 1997/9/1

N2 - Inverse gas chromatography (IGC) at infinite dilution was used to determine the dispersive component γSD of the surface energy of some metallic oxides and hydroxides. The zero charge point (ZCP) of these solids was determined by potentiometric measurements, whereas their isoelectric point (IEP) was calculated by the zeta potential technique in aqueous medium. This study allowed us to determine the acid-base properties (in terms of the Brönstedt acid-base concept) of the solids. The interfacial energy of the oxides and hydroxides was obtained from the results of Söhnel. The new linear relationships found between the γSD of solids and their ZCP (or their IEP, or pH of their aqueous suspension) allowed us to obtain the polar component of the surface energy as a function of the ZCP or IEP of these solids.

AB - Inverse gas chromatography (IGC) at infinite dilution was used to determine the dispersive component γSD of the surface energy of some metallic oxides and hydroxides. The zero charge point (ZCP) of these solids was determined by potentiometric measurements, whereas their isoelectric point (IEP) was calculated by the zeta potential technique in aqueous medium. This study allowed us to determine the acid-base properties (in terms of the Brönstedt acid-base concept) of the solids. The interfacial energy of the oxides and hydroxides was obtained from the results of Söhnel. The new linear relationships found between the γSD of solids and their ZCP (or their IEP, or pH of their aqueous suspension) allowed us to obtain the polar component of the surface energy as a function of the ZCP or IEP of these solids.

KW - inverse gas chromatography

KW - surface energy

KW - zero charge point

U2 - 10.1016/S1251-8069(97)81154-2

DO - 10.1016/S1251-8069(97)81154-2

M3 - Article

SN - 1287-4620

VL - 325

SP - 353

EP - 362

JO - Comptes Rendus de l'Académie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy

JF - Comptes Rendus de l'Académie des Sciences - Series IIB - Mechanics-Physics-Chemistry-Astronomy

IS - 6

ER -