An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals

Michał Magott; Maria Brzozowska; Stanisław Baran; Veacheslav Vieru; Dawid Pinkowicz

doi:10.1038/s41467-022-29624-7

An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals

Michał Magott, Maria Brzozowska, Stanisław Baran, Veacheslav Vieru, Dawid Pinkowicz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high density data storage. Thus, novel strategies on how to design MNMs are desirable. Here, inspired by the hexagonal structure of the hardest intermetallic magnet SmCo5, we have synthesized a nanomagnetic molecule where the central lanthanide (Ln) ErIII is coordinated solely by three transition metal ions (TM) in a perfectly trigonal planar fashion. This intermetallic molecule [ErIII(ReICp2)3] (ErRe3) starts a family of molecular nanomagnets (MNM) with unsupported Ln-TM bonds and paves the way towards molecular intermetallics with strong direct magnetic exchange interactions-a promising route towards high-performance single-molecule magnets.

Original language	English
Article number	2014
Number of pages	7
Journal	Nature Communications
Volume	13
Issue number	1
DOIs	https://doi.org/10.1038/s41467-022-29624-7
Publication status	Published - 19 Apr 2022

Keywords

ANISOTROPY
BARRIER
COMPLEXES
CRYSTAL-STRUCTURE
MAGNETIC-PROPERTIES
RELAXATION

Access to Document

10.1038/s41467-022-29624-7Licence: CC BY

CCDC 2065530: Experimental Crystal Structure Determination
Magott, M. (Contributor), Brzozowska, M. (Contributor), Baran, S. (Contributor), Vieru, V. (Contributor) & Pinkowicz, D. (Creator), Cambridge Crystallographic Data Centre, 28 Feb 2021
DOI: 10.5517/ccdc.csd.cc27bc0z
Dataset/Software: Dataset
CCDC 2065531: Experimental Crystal Structure Determination
Magott, M. (Contributor), Brzozowska, M. (Contributor), Baran, S. (Contributor), Vieru, V. (Contributor) & Pinkowicz, D. (Creator), Cambridge Crystallographic Data Centre, 28 Feb 2022
DOI: 10.5517/ccdc.csd.cc27bc10
Dataset/Software: Dataset

Cite this

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abstract = "Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high density data storage. Thus, novel strategies on how to design MNMs are desirable. Here, inspired by the hexagonal structure of the hardest intermetallic magnet SmCo5, we have synthesized a nanomagnetic molecule where the central lanthanide (Ln) ErIII is coordinated solely by three transition metal ions (TM) in a perfectly trigonal planar fashion. This intermetallic molecule [ErIII(ReICp2)3] (ErRe3) starts a family of molecular nanomagnets (MNM) with unsupported Ln-TM bonds and paves the way towards molecular intermetallics with strong direct magnetic exchange interactions-a promising route towards high-performance single-molecule magnets.",

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AU - Pinkowicz, Dawid

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AB - Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high density data storage. Thus, novel strategies on how to design MNMs are desirable. Here, inspired by the hexagonal structure of the hardest intermetallic magnet SmCo5, we have synthesized a nanomagnetic molecule where the central lanthanide (Ln) ErIII is coordinated solely by three transition metal ions (TM) in a perfectly trigonal planar fashion. This intermetallic molecule [ErIII(ReICp2)3] (ErRe3) starts a family of molecular nanomagnets (MNM) with unsupported Ln-TM bonds and paves the way towards molecular intermetallics with strong direct magnetic exchange interactions-a promising route towards high-performance single-molecule magnets.

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KW - BARRIER

KW - COMPLEXES

KW - CRYSTAL-STRUCTURE

KW - MAGNETIC-PROPERTIES

KW - RELAXATION

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An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals

Abstract

Keywords

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Datasets

CCDC 2065530: Experimental Crystal Structure Determination

CCDC 2065531: Experimental Crystal Structure Determination

Cite this